Limited User Account Issues On Startup

So I am very familiar with windows 7 and stuff, and for obvious security reasons I don't want to use a an administrator account just to browse the net and do day to day activities like most people do and then wonder why they have malware. So I have installed some software from the administrator account that was originally created during install and then I changed that account to a standard user account and created a separate administrator privileged account named admin. All should be good right? When windows starts up now in the standard user account that I want to use most of the time I need to use my password for certain startup programs like core temp i.e. you have to verify you want to them to run using the administrative password. What if I don't want to do this? I just want them to run without the password? I tried going in and changing the permissions to allow full control for authenticated users and my standard user account but it still asks for a password on log on.