How To Transfer Outlook 2010 Data Desktop To Laptop

I purchased Outlook 2010 out-of-the-box and am authorized to install it on two machines. It's been running on my desktop (duo-core Intel/Windows 7 64bit) for months now, and I've just gotten around to installing it on my Toshiba Satellite (Athlon/Windows 7 32bit) laptop.

So far, so good, but I don't want to have to manually and tediously set up my email accounts again. let alone copy calendar and notes, etc. How do I transfer all that data over? It'll be especially important when synchronizing the two machines. I tried copying over the C:User...AppDataLocalMicrosoftOutlook folder with contents and C:User...AppDataRoamingMicrosoftOutlook folder as well. No apparent effect.

It used to be that copying Outlook.pst would do the trick, but no longer, apparently.